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dc.contributor.authorCampos, Pablo Teles Aragão-
dc.contributor.authorOliveira, Claudinei Fabiano-
dc.contributor.authorLima, João Pedro Vieira-
dc.contributor.authorSilva, Daniele Renata de Queiroz-
dc.contributor.authorDias, Sílvia Cláudia Loureiro-
dc.contributor.authorDias, José Alves-
dc.date.accessioned2022-08-22T22:37:55Z-
dc.date.available2022-08-22T22:37:55Z-
dc.date.issued2021-
dc.identifier.citationCAMPOS, Pablo Teles Aragão et al. Cerium–zirconium mixed oxide synthesized by sol-gel method and its effect on the oxygen vacancy and specific surface area. Journal of Solid State Chemistry, v. 307, art. 122752, mar. 2022. DOI 10.1016/j.jssc.2021.122752. Disponível em: https://www.sciencedirect.com/sdfe/reader/pii/S0022459621007970/pdf. Acesso em: 22 ago. 2022.pt_BR
dc.identifier.urihttps://repositorio.unb.br/handle/10482/44617-
dc.language.isoInglêspt_BR
dc.publisherElsevierpt_BR
dc.rightsAcesso Restritopt_BR
dc.titleCerium–zirconium mixed oxide synthesized by sol-gel method and its effect on the oxygen vacancy and specific surface areapt_BR
dc.typeArtigopt_BR
dc.subject.keywordNanoestruturaspt_BR
dc.subject.keywordÓxido de zincopt_BR
dc.subject.keywordÓxido de cériopt_BR
dc.identifier.doihttps://doi.org/10.1016/j.jssc.2021.122752pt_BR
dc.description.abstract1In this study, cerium-zirconium mixed oxides were prepared using the sol-gel methodology with cetyltrimethylammonium bromide (CTAB) for tuning the specific surface area and pore volume. The composition of Ce0.8Zr0.2O2 (CZ) was selected as being one of the most active for soot oxidation, which is a concern as an environmental pollutant. The structural and morphological properties were investigated using EDXRF, XRD, SEM/EDS, Raman and N2 physisorption at low temperature. The catalytic test was evaluated by temperatureprogrammed oxidation coupled with mass spectrometry (TPO/MS). Any variation in the CTAB concentration during synthesis changed the particle size and surface area, indicating that the particle formation follows a mechanism in which the CTAB acts as capping agent. Additionally, the material synthesized with CTAB was found to have higher oxygen vacancy compared to the materials from the conventional sol-gel process. The catalytic test suggested that the material with the smallest surface area had the lowest temperature of oxidation (T50% = 400o C), which demonstrates that the oxygen vacancy parameter is essentially more important than the specific surface area itself.pt_BR
dc.contributor.emailmailto:jdias@unb.brpt_BR
dc.description.unidadeInstituto de Química (IQ)pt_BR
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