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dc.contributor.authorLenz, Guilherme Felipe-
dc.contributor.authorSchneider, Rodrigo-
dc.contributor.authorAguiar, Kelen M. F. Rossi de-
dc.contributor.authorBini, Rafael A.-
dc.contributor.authorChaker, Juliano Alexandre-
dc.contributor.authorHammer, Peter-
dc.contributor.authorBotteselle, Giancarlo V.-
dc.contributor.authorFelix, Jorlandio Francisco-
dc.contributor.authorSchneider, Ricardo-
dc.date.accessioned2020-03-04T11:28:39Z-
dc.date.available2020-03-04T11:28:39Z-
dc.date.issued2019-05-31-
dc.identifier.citationLENZ, Guilherme Felipe et al. Self-supported nickel nanoparticles on germanophosphate glasses: synthesis and applications in catalysis. RSC Advances, v. 9, n. 30, p. 17157–17164, 31 maio 2019. DOI: 10.1039/c9ra02927c. Disponível em: https://pubs.rsc.org/en/content/articlelanding/2019/ra/c9ra02927c#!divAbstract. Acesso em: 04 mar. 2020.pt_BR
dc.identifier.urihttps://repositorio.unb.br/handle/10482/37043-
dc.language.isoInglêspt_BR
dc.publisherRoyal Society of Chemistrypt_BR
dc.rightsAcesso Abertopt_BR
dc.titleSelf-supported nickel nanoparticles on germanophosphate glasses : synthesis and applications in catalysispt_BR
dc.typeArtigopt_BR
dc.subject.keywordNanopartículaspt_BR
dc.subject.keywordNíquelpt_BR
dc.subject.keywordCatalisadorespt_BR
dc.rights.license(CC BY) - Open Access Article. Published on 31 May 2019. Downloaded on 2/28/2020 2:08:34 PM. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.pt_BR
dc.identifier.doi10.1039/c9ra02927cpt_BR
dc.description.abstract1The development of supported catalysts based on simple procedures without waste products and timeconsuming steps is highly desirable. In this paper, self-supported nickel-based nanoparticles were obtained at the surface of the germanophosphate glasses by bottom-up process and evaluated as potential catalysts for the benzyl alcohol oxidation and bis(indolyl)methanes synthesis. A classical meltquenching technique was used for preparing the nickel-doped germanophosphate glasses, followed by annealing under a hydrogen atmosphere at 400 C for two different times. The approach enabled the synthesis of self-supported nanoparticles as a homogeneous film, covering the glass surface. The physical and chemical properties of synthesized glasses were characterized by UV-vis and Raman spectroscopies and thermal analysis. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were performed to monitor the growth process, morphology and chemical bonding structure of the nanoparticles surface.pt_BR
dc.description.unidadeInstituto de Química (IQ)pt_BR
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